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c/hplc·submitted 4 days ago by u/peak_area_pete

[Correction] you cannot report area% to two decimals off that baseline

Correctionbranch of 4 comments

Not naming the poster, the trace is in the thread below this one and they will know. The reported figure is 98.47%. The baseline in the attached trace drifts visibly across the run and there is noise of roughly the same magnitude as the smallest reported impurity. You cannot resolve a hundredth of a percent off that.…

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4 comments, started 3 days ago
u/tared_twice154 points·3 days ago

the same instinct applies to weighing. an analytical balance reading to five places does not mean your sample mass is known to five places once you have opened the door.

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u/peak_area_peteOPanalytical118 points·3 days ago

yes, and it is the same failure — trusting the display over the process.

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u/baseline_drifteranalytical96 points·3 days ago

if your baseline wanders your integration lies, and every digit after the first decimal is the lie getting more confident.

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u/quant_not_qual74 points·3 days ago

i want this on a poster

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